Analysis of slurry flow in chemicalmechanical polishing. Slurry chemistry effects on copper chemical mechanical. This paper deals with the study of the effect of primary slurry parameters on the plate weight ceramic retention test in ceramic shell investment casting process. Cmp processes, tools and slurries utilize composite particles that include core. Four controllable factors of the zircon flour and fusedsilica powder based slurries were studied at three levels each by taguchis parametric approach and singleresponse optimization of plate weight was conducted to identify. December 14, 2011 the dow chemical company page 5 of 7 other for slurries containing silica abrasives, there is. Nanocrystalline diamond ncd thin films grown by chemical vapour deposition have an intrinsic surface roughness, which hinders the. Lynn fuller, professor cmp page 2 rochester institute of technology microelectronic engineering cmp chemical mechanical planarization. The composition of the slurry was 5 vol % h3po4 1 0. Electrochemical behavior of aluminum during chemical mechanical polishing in phosphoric acid base slurry hongshi kuo and wenta tsai department of materials science and engineering, national cheng kung university, tainan, taiwan the electrochemical behavior of aluminum in chemical mechanical polishing cmp slurry was investigated using.
Effect of slurry composition on plate weight in ceramic. Chemical mechanical planarization solutions chemical mechanical planarization cmp is a polishing process, which utilizes a chemical slurry formulation and mechanical polishing process to remove unwanted conductive or dielectric materials on the silicon wafer, achieving a nearperfect flat and smooth surface upon which layers of integrated circuitry are built. The slurry temperature was controlled at 25 6 28c during static and polishing state tests. Experimental and numerical analysis of an inhibitor. Osseoasare department of materials science and engineering the pennsylvania state university university park, pa 16802 cerium oxide, ceria ceo2, has been widely used as an abrasive in glass polishing and in semiconductor fabrication. Chemical mechanical polishing slurry for amorphous. Chemical mechanical polishing of copper using nanoparticle. Nanomaterials nm of silica sio 2, cerium ceo 2, and alumina al 2 o 3 are used in liquid slurries by a number of industrial applications, including chemical mechanical polishing planarization cmp processes used multiple times during production of computer chips. But the dependence of kp on process variables like slurry composition and pad. Chemicalmechanical polishing slurry formulation and method for tungsten and. Chemical mechanical polishing slurry for amorphous ge 2. The composition of the test slurry is shown in table ii.
Effect of slurry composition on the chemical mechanical polishing of thin diamond films jessica m. Effect of slurry composition on the chemical mechanical. The effect of slurry composition and flatness on subsurface. This phase stops at the surface of the barrier layer. An improved slurry composition and method of polishing a workpiece are disclosed. Slurry cmp resources are compiled in this industrial portal which provides information on manufacturers, distributors and service companies in the semiconductor analysis. The process uses an abrasive and corrosive chemical slurry commonly a colloid in conjunction with a polishing pad and retaining ring, typically of a greater diameter than the wafer. Mrr 220 nmmin with 2 wt% h2o2 mrr prediction and particle size for alumina with cu slurry additives mrr 110 nmmin particle size 0. Three mct wafers were distributed on the periphery of a circular plate of aluminium alloy in diameter of 150 mm. It has been found that such a slurry produces a high material removal rate for barium strontium titanate bst polishing, without damage to the surface of the bst workpiece commonly found with other slurry compositions. A dynamic measurement of the slurry properties coupled. Our team of industryexperienced cmp professionals brings its knowledge to bear on every customer interaction to complete yield analysis on first.
A dynamic measurement of the slurry properties coupled with defined control limits can be used to determine a slurry health. Chemical mechanical polishing, cabot microelectronics. Polishing with slurry a cleaner polishing with slurry b cleaner. Wo2016024177a1 chemicalmechanical polishing composition. Chemical mechanical polishing or planarization is a process of smoothing surfaces with the combination of chemical and mechanical forces. Chemical mechanical planarization cmp is a wet polishing technique employed to smooth the surface of various materials using a combination of chemical and mechanical forces to achieve finer and longer lines on semiconductor devices. Effect of slurry composition on the chemical mechanical polishing of thin diamond films. The effect of slurry composition and wafer flatness on a material removal rate mrr and resulting surface roughness which are evaluation parameters to determine the cmp characteristics of the on. Chemical mechanical planarization cmp slurries selection. There are 1,717 suppliers who sells chemical mechanical polishing on, mainly located in asia. Chemical mechanical polishing cmp is a finishing process that is used to prepare substrates for electronic devices. Pdf chemical mechanical polishing slurry for amorphous.
The electrochemical behavior of aluminum in chemical. A cupric salt cmp slurry was employed to improve the throughput and surface finish on a conventional polishing machine. A chemical mechanical polishing slurry is used to wet the polishing surface 26 and contains an abrasive to facilitate mechanical polishing of the integrated circuit structure 10. Chemicalmechanical polishing of lowdielectricconstant. Another aspect of this invention is a chemical mechanical. Control of nanomaterials used in chemical mechanical. Effects of slurry formulations on chemicalmechanical. In this study, the film properties and chemicalmechanical polishing cmp characteristics of the low dielectric constant polymers hydridoorgano siloxane and methyl silsesquioxane are presented. Figure 4 further shows the particle size of acidic slurry and alkaline slurry as a function of collection time during polishing of gst. Abrasive effects in oxide chemical mechanical polishing mrs. Chemicalmechanical polishing cmp is often associated with chemicalmechanical planarization which is a polishing process assisted by chemical reactions to remove surface materials. The effect of slurry composition and flatness on sub. A wide variety of chemical mechanical polishing options are available to you, such as stainless steel.
Chemical mechanical planarization pt01003jt 4 a 2phase process is adopted in our inlaid copper pattern wafer polishing, which means changing slurry and working conditions during the copper. Cerium oxide slurries in chemical mechanical polishing. The polishing was carried out using the commercial slurry procured from cabot. Beijing university of aeronautics and astronautics, 1994 a thesis submitted in partial fulfillment of. The composition of cmp slurry wastewaters is described, along with the. A typical cmp process mainly consists of th ree components. Chemical mechanical polishing slurry for amorphous ge2sb2te5. Welcome to the most trusted and comprehensive semiconductor analysis. White, lamon jones and richard romine cabot microelectronic corp.
Electrochemical analysis of the slurry composition for. Electrochemical behavior of aluminum during chemical. The copper wafers were characterized by afm in order to analyze surface roughness. Us patent for chemical mechanical planarization slurry composition. Cmp is a surface polishing and material removal process involving both chemical attack and abrasive removal. A novel approach of chemical mechanical polishing using. The slurries can be hand sprayed onto the lappingpolishing platen or. The present invention provides a slurry composition for chemical mechanical polishing comprising spinel particles having the formula aoxz 2 o 3 wherein a is at least one divalent cation, z is at least one trivalent cation, and 0. The mechanism of low ph silica based oxide slurries michael l. The goal of the 1st phase cmp is to remove copper layer with high efficiency.
This composition allows use of a neutral ph slurry for chemicalmechanical polishing many surfaces. Chemical mechanical polishing and cleaning cleaning paradigm need to be shifted. Cmp chemical mechanical planarization customers just starting in cmp or considering implementing the process find substantial benefits from utilizing entrepix cmp fast forward services. Slurry chemical mechanical polishing cmp semiconductor analysis. As the amount of organic content in sog increases, the chemicalmechanical polishing cmp removal rate. Chemical mechanical planarization cmp slurries are liquid dispersions. The solid lines are model predictions using surface layer thickness t as the fitting.
The chemical mechanical polishing process is continued until the structure 10 is effectively planarized. Analysis of slurry flow in chemical mechanical polishing by krzysztof d. Figure 2 shows the optical images of surface morphologies after fixedabrasive lapping by alumina with a size of 5. Polishing pressure as well as the flow rate of the polishing slurry and rotation of the polishing pad determine the fluidynamics of the polishing process.
Kopanski submitted to the department of mechanical engineering on may 23, 2005 in partial fulfillment of the requirements for. Slurry components in metal chemical mechanical planarization cmp process. A slurry composition for chemical mechanical polishing cmp of a phasechange memory device is provided. Effect of applied potential on the chemical mechanical. Chemical mechanical planarization pt01003jt 4 a 2phase process is adopted in our inlaid copper pattern wafer polishing, which means changing slurry and working conditions during the copper removal process. Chemical mechanical planarization of electronic materials. Effect of slurry composition on the chemical mechanical polishing of. The slurry composition comprises deionized water and iron or an iron compound. The concept of chemical mechanical planarization cmp was. Osseoasare department of materials science and engineering the pennsylvania state university. The lapmaster range of diamond slurries has been formulated for use on many different types of lapping plates and polishing pads.
Chemical mechanical polishing slurry for amorphous ge2sb2te5 zhitang song1,2, weili liu1,2, liangyong wang1,2 1shanghai institute of. In order to avoid the environmental pollution and the harm to body of traditional polishing slurries, an environmentfriendly chemical mechanical polishing technology is proposed for sic wafer in this. Specifically designed for optimal polishing performance on cplane sapphire, saintgobains 9221 nano alumina slurry offers a slight modification to the crystal structure. To achieve a scratchfree planar surface, the slurry chemistry needs to be adjusted so that the polishing rate is balanced between the chemical and.
Cmp is a standard manufacturing process practiced at the semiconductor industry to fabricate integrated circuits and memory disks. Removal rate shelf life silicon nitride fumed silica settling rate. Polycrystalline alumina polishing slurries products. During conventional polishing, both the rotation rates of polishing pads and mct wafers were 40 rpm. Slurry chemical mechanical planarization cmp slurries. Lastly, cmp behavior of copper wafer was examined under different polishing conditions. Analysis of slurry flow in chemicalmechanical polishing by krzysztof d. Both for the slurries at ph2 and ph11, the mean particle size is around 65nm with a variation within f3nm. Chemicalmechanical planarization of semiconductor materials pp 215249 cite as. The cmp slurry composition is an important factor because additives in the slurry generally improve the polishing performance. Abrasive effects in oxide chemical mechanical polishing. Dielectric chemical mechanical polishing cmp was implemented in semiconductor. The cmp slurry composition is an important factor because.
Study of conditioner abrasives and synthesis of nanozirconia for potential slurry applications by chhavi manocha a thesis submitted in partial fulfillment of the requirements for the degree of master of chemical engineering department of chemical and biomedical engineering college of engineering. New to cmp cmp chemical mechanical planarization customers just starting in cmp or considering implementing the process find substantial benefits from utilizing entrepix cmp fast forward. Us4954142a method of chemicalmechanical polishing an. Chemical mechanical polishing, cabot microelectronics cmp. Described are a chemicalmechanical polishing cmp composition. The slurry flow controls the supply and the exchange of chemical compounds at the silicon surface and the removal of the reaction products.
The mechanism of low ph silica based oxide slurries. Chemical mechanical planarization cmp slurries are liquid dispersions containing active chemicals and microabrasive grains used for chemical mechanical planarization. The molecular structure and film properties of both polymers were characterized by their fourier transform infrared spectra, refractive indices, dielectric constants, and atomic force microscopy. Slurry chemical mechanical polishing cmp semiconductor. In this study, we have characterized the effects of abrasive properties, primarily particle size, on the chemical mechanical polishing cmp of oxide films. Study of conditioner abrasives and synthesis of nanozirconia for potential slurry applications by chhavi manocha a thesis submitted in partial fulfillment of the.
Chemical mechanical planarization cmp slurries selection guide. Disclosed is a method of chemmech polishing an electronic component substrate. Chemical mechanical polishing planarization cmp is a critical step in semiconductor manufacturing. Chemical mechanical planarization slurry composition comprising. Slurry components in metal chemical mechanical planarization. Wo1998023408a1 a composition and slurry useful for metal cmp. Furthermore, the cmp composition of the invention should have a long shelf life. Kopanski submitted to the department of mechanical engineering on may 23, 2005 in partial fulfillment of the requirements for the degree of master of science in mechanical engineering abstract chemical mechanical polishing cmp is one of the enabling processes used in. Chemical mechanical planarization for microelectronics applications. Cmp technological paradigm shift to surface cleaning. Aurora, il 60504 abstract the mechanism of oxide polishing at low ph in the presence of an organic cation is discussed. Phosphoric acid base slurry containing alumina powders was prepared. Chemicalmechanical planarization cmp slurries created.
Wo1998042791a1 chemicalmechanical polishing slurry. The slurry composition for chemical mechanical polishing of metal layer on semiconductor substrates, comprising hydrogen peroxide, nitric acid, malic acid, a silica abrasive in an amount exceeding 8 wt %, a fepropylenediaminetetraacetate fepdta complex and deionized water. A wide variety of chemical mechanical polishing options are available. The slurries can be hand sprayed onto the lapping polishing platen or applied by an electronic dispensing system to control cost and reduce waste.
Pdf chemical mechanical polishing slurry of copper usually contains more than four compositions, in which strong acids, alkalis or hazardous. Chemical mechanical polishing includes traditional polishing, eg. This invention is also a chemical mechanical polishing slurry and composition that has a long shelf life. Pdf slurry components in metal chemical mechanical. In order to make the polishing slurry distribution more uniform over the polishing region, a new kind of polishing pad, which has sunflower seed pattern, has been designed based on the. Nov 07, 2000 a chemical mechanical polishing slurry is used to wet the polishing surface 26 and contains an abrasive to facilitate mechanical polishing of the integrated circuit structure 10. The slurry was tailored later to reduce defects and surface nonplanarity introduced by the. Pdf environment friendly chemical mechanical polishing of copper. Effect of slurry composition on plate weight in ceramic shell. Ee143 f2010 lecture 17 wafer is polished using a slurry containing silica abrasives 1090 nm particle size etching agents e. From table 1, it can be found that among all contact area values for the polishing slurry compositions of comparative examples 11 and 12 and examples 11 to 16, the polishing slurry. Slurry containing mainly pure water, a chemical reagent and different polishing particles are used between the polishing pad and the wafer. Environmentfriendly chemical mechanical polishing slurry.
However, it is limited to find the optimum conditions for the slurry by only experimental approaches. Cmp technological paradigm shift to surface cleaning hong jin kim. Kr1016359b1 nano ceria slurry composition for chemical. Chemical mechanical polishing cmp is the planarization method that has been selected by the. The new process was faster than the previous silica based polishing method and resulted in a mirrorlike surface blake and mendel, 1970. Triboelectrochemical investigation of a slurry composition to reduce dissolution and galvanic corrosion during chemical mechanical planarization of curu interconnects. Solgel silica particles with very narrow size distributions were used for preparing the polishing slurries. Microelectronic applications of chemical mechanical planarization edited by yuzhuo li.
Us6251150b1 slurry composition and method of chemical. Chemical mechanical polishing composition and method of. Nanomaterials nm of silica sio 2, cerium ceo 2, and alumina al 2 o 3 are used in liquid slurries by a number of industrial applications, including chemical mechanical polishingplanarization cmp. Shelf life can be an important consideration for readymade slurries and. It can be thought of as a hybrid of chemical etching and free abrasive polishing. The polishing was carried out using the commercial slurry procured from cabot microelectronics inc. In this study, the film properties and chemical mechanical polishing cmp characteristics of the low dielectric constant polymers hydridoorgano siloxane and methyl silsesquioxane are presented. Science and technology of advanced materials 2017, 18 1, 654663. The transformation in electronic devices that has occurred in the past few decades has relied greatly on the efficiency and effectiveness of planarization using slurry polishing. Chemical mechanical planarization cabot microelectronics. Chemical mechanical planarization solutions chemical mechanical planarization cmp is a polishing process, which utilizes a chemical slurry formulation and mechanical polishing process to remove. The effect of slurry composition and wafer flatness on a material removal rate mrr and resulting surface roughness which are evaluation parameters to determine the cmp characteristics of the onaxis 6hsic substrate were systematically investigated. The polishing slurry provides the mean s by which both chemical and mechanical tribological actions are used to remove and subsequently planarize the wafer surface. The nanoceria composition for chemical mechanical polishing according to an embodiment of the present invention can ensure high dispersibility of abrasive grains in a slurry composition even without a separate dispersion aid and can improve the removal rate of the conventional slurry slurry for cmp, the degree of roughness of the wafer is improved and the influence on the scratch of the wafer can be effectively suppressed.
The new process was faster than the previous silica based polishing method and. Ee143 f2010 lecture 17 university of california, berkeley. Jan 26, 2017 from table 1, it can be found that among all contact area values for the polishing slurry compositions of comparative examples 11 and 12 and examples 11 to 16, the polishing slurry compositions of examples to 16 in which three types of silica abrasive particles were mixed have relatively high contact area values, and the polishing slurry compositions of examples 11 and 12 in which. In conventional polishing, free abrasives of alumina were used with size of 1. One disclosed composition comprises 85% water, 4% nacl, 4% h 2 o 2, and 7% colloidal silica.
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